Read e-book online Coherent Synchronized Oxidation Reactions by Hydrogen PDF

By Tofik M. Nagiev

ISBN-10: 0444528512

ISBN-13: 9780444528513

Describes the family among reactions in chemical and biochemical platforms with exact emphasis to excessive selective oxidation reactions by means of hydrogen peroxide.Outlines attainable methods for the appliance of those reactions in an commercial scale. * taking a look at new ways to the synthesis and learn of catalytic natural reactions through hydrogen peroxide* Discussing the real advancements within the quarter of biomimetic catalysis* masking biomimetic sensors, the hot iteration of analytical units and their purposes

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Extra resources for Coherent Synchronized Oxidation Reactions by Hydrogen Peroxide

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68, pp. 1686–1689. 15. , 1962, Vol. 84, p. 774. 16. , Free Radicals, Atomizdat, Moscow, 1970, 335 pp. (in Russian). 17. M. , The Course Of Chemical Kinetics, Vyssh. Shkola, Moscow, 1984, 237 pp. (in Russian). 18. , The Mechanism of Hydrocarbons Oxidation in Liquids, Izd. AN SSSR, Moscow, 1960, 496 pp. (in Russian). 19. , On Some Problems in Chemical Kinetics and Reactivity, 2nd edn, Izd. AN SSSR, Moscow, 1958, 680 pp. (in Russian). 20. , Meerbott, W. , J. Am. Chem. , 1953, Vol. 75, pp. 1809–1814.

The following typical features of conjugated reactions may be distinguished: 1. 2. 3. 4. 5. e. free energy drop in the primary reaction fully covers the increase of free energy in the secondary reaction. It is also possible that spontaneous (secondary) reaction is accelerated, proceeding with the free energy decrease, but under current conditions its rate may be negligibly low (for instance, equal almost zero). The principle of independent proceeding of elementary chemical reactions is not fulfilled.

Line location above the X line means that the greater part of the total, highly active intermediate particles (active sites) is consumed for secondary reaction product formation and, vice versa, when the line is below X level. 2a. It is known that the correspondence principle suggested by N. Bohr (1923) postulates that ‘any theory pretending for better description and broader application range than the older one must include the latter in the form of marginal case’. The succession of theoretical notions may be shown by using the corresponding principle for consideration of the chemical interference theory as a more general concept of interrelated and interacting reactions.

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Coherent Synchronized Oxidation Reactions by Hydrogen Peroxide by Tofik M. Nagiev

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