Catalysts for Fine Chemical Synthesis, Hydrolysis, Oxidation by Stanley M. Roberts, Geraldine Poignant PDF

By Stanley M. Roberts, Geraldine Poignant

ISBN-10: 0471981230

ISBN-13: 9780471981237

Catalysts are more and more utilized by chemists engaged in nice chemical synthesis inside either and academia. at the present time, there exists an incredible selection of high-tech catalysts, which upload drastically to the repertoire of man-made percentages. besides the fact that, catalysts are sometimes capricious, occasionally tricky to take advantage of and mainly require either ability and event that allows you to in achieving optimum effects. This sequence goals to be a pragmatic aid for complicated undergraduate, graduate and postgraduate scholars, in addition to skilled chemists in and academia operating in natural and organometallic synthesis. The sequence good points: * demonstrated and established tactics. * Authoritative stories on periods of catalysts. * exams of every kind of catalysts. * services from the Leverhulme Centre for cutting edge Catalysis, Liverpool, united kingdom. The overview part within the first quantity of the sequence encompasses a document by means of Stanley M. Roberts at the integration of biotransformations into the catalyst portfolio. The strategy part incorporates a big range of artificial protocols, akin to epoxidations of unsaturated ketones and esters, uneven discount rates of carbon-oxygen double bonds, uneven hydrogenations of carbon-carbon double bonds and different kinds of response. The featured catalysts contain quite a lot of assorted fabrics similar to poly-D-leucine, D-fructose-based dioxiranes, oxaborolidine borane, a few vital titanium and ruthenium complexes in addition to baker's yeast. for every response there are one or numerous special protocols on how one can arrange and hire a number of the catalysts.

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Extra resources for Catalysts for Fine Chemical Synthesis, Hydrolysis, Oxidation and Reduction

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L. H. J. Am. Chem. , 1999, 121, 4284. -F. and Mortreux, A. Chem. A. and Cornils, B. Angew. Chem. Int. Ed. , 1997, 36, 1048; I. J. L. J. Organomet. , 1997, 540, 15. , Nozaki, K. and Takaya, H. J. Am. Chem. , Horiuchi, T. and Takaya, H. ibid, 1997, 119, 4413. Alper, H. and Hamel, N. J. Am. Chem. , Fu, H. and Wang, H. J. Organomet. , 1997, 543, 227. , Park, H. V. J. Am. Chem. , 1998, 120, 459. , Keim, W. and Vogt, D. J. Organomet. , 1998, 552, 187. Aratani, T. Pure Appl. , 1985, 57, 1839. A. and Ye, T.

Sasai, H. and Shibasaki, M. J. Am. Chem. , 1999, 121, 4168. 129. An excellent overview of the stereochemistry of the aldol reaction is given by Procter, G. in Asymmetric Synthesis, Chapter 5, pp. 69±101, OUP, Oxford, 1996. 130. , Sarshar, S. -H. J. Am. Chem. , 1994, 116, 12089. 131. R. D. J. Am. Chem. , 1997, 119, 10551. 132. J. -P. J. Am. Chem. , 1991, 113, 8966. 133. , Ito, K. and Itsuno, S. J. Org. , 1996, 61, 8321. 134. , Kurihara, H. and Yamamoto, H. J. Org. , 1997, 62, 3026. 135. A. M. , 1997, 38, 3193.

W. J. Chem. , Chem. , 1988, 509. 7. , Ohno, A. , 1989, 30, 2245 and references therein. 8. W. J. Chem. , Perkin Trans. 1, 1997, 2179. 9. , Renhowe, P. J. Org. , 1992, 57, 4329. W. J. Org. , 1999, 64, 6434. Catalysts for Fine Chemical Synthesis: Hydrolysis, Oxidation and Reduction. Volume 1 Edited by Stan M Roberts and Geraldine Poignant Copyright  2002 John Wiley & Sons, Ltd. 4 Introduction . . . . . . . . . . Oxazaborolidine borane reduction of acetophenone . . . . Oxazaphosphinamide borane reduction of chloroacetophenone .

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Catalysts for Fine Chemical Synthesis, Hydrolysis, Oxidation and Reduction by Stanley M. Roberts, Geraldine Poignant


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